Great for a second attempt! I like her eyes and lips!
Make sure when you shade you have the box with the words anti-alias next to it selected. The edges of your shading are choppy and this should help smooth the edges. Also more layers or smoother shapes will help too.
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Thank you for your comment! Sorry to answer so late....What anti-alias is,...I have cs spanish version...i was searching it in tutorials but I didn't find it :(. In the new vexel i add I do more layers but i'm bad shading.....